Kinetics and mechanism of catalysed and uncatalysed oxidation of D-glucose by N-bromosuccinimide in aqueous acidic medium

被引：0

作者：

Rajput, Surendra Kumar ^{[1
]}

Sharma, Aarti ^{[1
]}

Chandrakar, Priyamvada ^{[1
]}

机构：

[1] Govt Coll Sci, Dept Chem, Raipur 492010, Madhya Pradesh, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2007年 / 84卷 / 08期

关键词：

D-Glucose; N-bromosuccinimide; catalysed reaction; oxidation;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetics of oxidation of D-glucose by N-bomosuccinimide (NBS) in presence of sulphuric acid, KC1, mercuric acetate and acetic acid have been investigated. The observed rate of oxidation is first order with respect to oxidant [NBS] both in the presence and absence of catalysts. A decrease in the dielectric constant of medium decreases the rate. Addition of succinimide [SA], has a retarding effect on the rate of oxidation. Increase in [H+] retards the reaction rate. Activation parameters have been calculated. A suitable mechanism has been proposed.

引用

页码：777 / 780

页数：4

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