Bis(3,5-dicarboxybenzoato-κ2O,O′)(1,10-phenanthroline)cobalt(II)

被引:2
作者
Han, JY [1 ]
Wei, WY [1 ]
Dou, X [1 ]
Chang, HY [1 ]
机构
[1] Tianjin Univ, Key Lab Green Chem Technol, State Educ Minist, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
关键词
D O I
10.1107/S1600536805032058
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title molecule, [Co(C9H5O6)(2)(C12H8N2)] or [Co(H2BTC)(2)(phen)] (BTC = benzene-1,3,5-tricarboxylate and phen = 1,10-phenanthroline), has crystallographic twofold symmetry. The Co-II atom has a coordination geometry that is intermediate between octahedral and trigonal prismatic. In the crystal structure, molecules are connected via O-H center dot center dot center dot O hydrogen bonds [O center dot center dot center dot O = 2.621 (4)-2.684 (4) angstrom] to form a three-dimensional network.
引用
收藏
页码:M2281 / M2282
页数:2
相关论文
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