Coordination of bimuth(III) to cucurbit[8]uril.: Preparation and X-ray structure of [{Bi(NO3)(H2O)5}2(Q8)][Bi(NO3)3(H2O)4]2[Bi(NO3)5]2•Q8.19H2O

被引：20

作者：

Sokolov, MN

Mitkina, TV

Gerasko, OA

Fedin, VP

Virovets, AV

Llusar, R

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, SB, Novosibirsk 630090, Russia

[2] Univ Jaume 1, Dept Ciencies Expt, Castellon de La Plana, Spain

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2003年 / 629卷 / 14期

关键词：

crystal structure; bismuth; cucurbituril;

D O I：

10.1002/zaac.200300298

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bi(NO3)(3) reacts with cucurbit[8]uril, (Q8), in 3M HNO3 to give the title complex whose structure includes three discrete Bi complexes: [{Bi(NO3)(H2O)(5)}(2)(Q8)](4+) (CN of Bi = 9, both NO3- and cucurbit[8]uril are bidentate), [Bi(NO3)(5)](2-) (CN of Bi = 10, all NO3- are bidentate), and [Bi(NO3)(3)(H2O)(4)] (CN of Bi = 10, all NO3- are bidentate).

引用

页码：2440 / 2442

页数：3

共 20 条

[1] CRYSTAL AND MOLECULAR-STRUCTURE OF BISTRIPHENYL(ETHYL)PHOSPHONIUM PENTANITRATOCERIUM(III) [J].