Solvothermal synthesis and structure of two 2D tin-selenides with long alkyldiamine NH2(CH2)nNH2 (n=8; 10)

被引：12
作者：
Lu, SM
Ke, YX
Li, JM [1 ]
Zhou, SX
Wu, XT
Du, WX
机构：
[1] Univ Sci & Technol China, Dept Chem Phys, Anhua 230026, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
STRUCTURAL CHEMISTRY | 2003年 / 14卷 / 06期
基金：
中国国家自然科学基金;
关键词：
solvothermal synthesis; crystal structure; tin-selenide compound; two-dimensional complex; organic amine; ion exchange;
D O I：
10.1023/B:STUC.0000007574.13596.f6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of NH2(CH2)(n)NH2 (n = 8, 10) with elemental Sn and Se in a H2O/CH3OH mixture at 150degreesC afford two compounds (NH3(CH2)(8)NH3)Sn3Se7 (1) and (NH3(CH2)(8)NH3)Sn3Se (2). The crystal structures were determined by single crystal X-ray diffraction at room temperature. Both compounds exhibit the same anionic structure-a 6(3) netted plane composed of [Sn3Se7](2-) subunits. The distance between the centers of crystal 1 layers is 7.5 Angstrom, somewhat shorter than the distance (8.5 Angstrom) in crystal 2.
引用
收藏
页码：637 / 642
页数：6
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