Solvothermal synthesis and structure of two 2D tin-selenides with long alkyldiamine NH2(CH2)nNH2 (n=8; 10)

被引：12

作者：

Lu, SM

Ke, YX

Li, JM ^{[1
]}

Zhou, SX

Wu, XT

Du, WX

机构：

[1] Univ Sci & Technol China, Dept Chem Phys, Anhua 230026, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

STRUCTURAL CHEMISTRY | 2003年 / 14卷 / 06期

基金：

中国国家自然科学基金;

关键词：

solvothermal synthesis; crystal structure; tin-selenide compound; two-dimensional complex; organic amine; ion exchange;

D O I：

10.1023/B:STUC.0000007574.13596.f6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of NH2(CH2)(n)NH2 (n = 8, 10) with elemental Sn and Se in a H2O/CH3OH mixture at 150degreesC afford two compounds (NH3(CH2)(8)NH3)Sn3Se7 (1) and (NH3(CH2)(8)NH3)Sn3Se (2). The crystal structures were determined by single crystal X-ray diffraction at room temperature. Both compounds exhibit the same anionic structure-a 6(3) netted plane composed of [Sn3Se7](2-) subunits. The distance between the centers of crystal 1 layers is 7.5 Angstrom, somewhat shorter than the distance (8.5 Angstrom) in crystal 2.

引用

页码：637 / 642

页数：6

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