Solvothermal synthesis and structure of two 2D tin-selenides with long alkyldiamine NH2(CH2)nNH2 (n=8; 10)

被引:12
作者
Lu, SM
Ke, YX
Li, JM [1 ]
Zhou, SX
Wu, XT
Du, WX
机构
[1] Univ Sci & Technol China, Dept Chem Phys, Anhua 230026, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
基金
中国国家自然科学基金;
关键词
solvothermal synthesis; crystal structure; tin-selenide compound; two-dimensional complex; organic amine; ion exchange;
D O I
10.1023/B:STUC.0000007574.13596.f6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reactions of NH2(CH2)(n)NH2 (n = 8, 10) with elemental Sn and Se in a H2O/CH3OH mixture at 150degreesC afford two compounds (NH3(CH2)(8)NH3)Sn3Se7 (1) and (NH3(CH2)(8)NH3)Sn3Se (2). The crystal structures were determined by single crystal X-ray diffraction at room temperature. Both compounds exhibit the same anionic structure-a 6(3) netted plane composed of [Sn3Se7](2-) subunits. The distance between the centers of crystal 1 layers is 7.5 Angstrom, somewhat shorter than the distance (8.5 Angstrom) in crystal 2.
引用
收藏
页码:637 / 642
页数:6
相关论文
共 50 条
  • [21] First representatives of (210)-oriented perovskite variants - Synthesis, crystal structures and properties of the new 2D hybrid perovskites A[HC(NH2)2]PbI4, A = [C(NH2)3], [HSC(NH2)2]
    Daub, Michael
    Hillebrecht, Harald
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2018, 233 (08): : 555 - 564
  • [22] Synthesis, structure, and characterization of a mixed amines thiogermanate [NH4]2[NH2(CH3)2]2Ge2S6
    Zhang, Jian-Han
    Su, Zhi-Zhong
    Luo, Ju-Xiang
    Zhao, Yi
    Wang, Hong-Gang
    Ying, Shao-Ming
    POLYHEDRON, 2020, 182
  • [23] Synthesis, structure characterization and biological activity of a novel polyoxovanadate cluster:: [NH3 (CH2)2 NH2 (CH2)2 NH3]4 • [V6V V12IVO42 (PO4)](PO4) • 2H2 O
    Fu, PP
    Wang, XL
    Wang, EB
    Qin, C
    Xu, L
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2005, 21 (04) : 381 - 385
  • [24] Synthesis and structure of a one-dimensional aluminum phosphate, [NH3(CH2)2NH2(CH2)3NH3]3+ ∞1[Al(PO4)2]3-
    Natarajan, S
    Klein, W
    Nuss, J
    van Wüllen, L
    Jansen, M
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (02): : 339 - 343
  • [25] The first organically templated layered uranium(IV) fluorides:: (H3N(CH2)3NH3)U2F10•2H2O, (H3N(CH2)4NH3)U2F10•3H2O, and (H3N(CH2)6NH3)U2F10•2H2O
    Francis, RJ
    Halasyamani, PS
    O'Hare, D
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (16) : 2214 - 2217
  • [26] Hydrothermal synthesis and structure of a new arsenic-vanadium cluster:: [NH2(CH2CH2)2NH2]3 [As8V14O42(SO4)]•6.5H2O
    Zheng, ST
    Zhang, H
    Yang, GY
    JOURNAL OF MOLECULAR STRUCTURE, 2004, 705 (1-3) : 127 - 132
  • [27] Synthesis and structure of a three-dimensional organically templated zinc ethylenediphosphonate, [NH3(CH2)2NH3][Zn3{O3P(CH2)2}4]
    Natarajan, S
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (02): : 291 - 295
  • [28] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE AMIDO PALLADATE (PPH4)2[PD2CL4(NH2)2].CH2CL2 AND OF THE BENZAMIDINE PALLADATE PPH4([PH-C(NH2)(NH)]PDCL3).CH3CN
    VONARNIM, H
    MASSA, W
    ZINN, A
    DEHNICKE, K
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (08): : 992 - 998
  • [29] Decavanadates with complex cations: synthesis and structure of (NH4)2[M(H2O)5(NH3CH2CH2COO)]2V10O28•nH2O (M = ZnII, n=4; M = MnII, n=2)
    Klistincova, Lenka
    Rakovsky, Erik
    Schwendt, Peter
    TRANSITION METAL CHEMISTRY, 2010, 35 (02) : 229 - 236
  • [30] Synthesis, crystal structure and activity study of 2D polymeric complex [MnNa(salicylate)2(CH3OH)(H2O)]n • 0.5nH2O
    Shi, W
    Xu, YK
    Wang, HM
    Liu, Y
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2003, 24 (03): : 516 - 518