Solvothermal synthesis and structure of two 2D tin-selenides with long alkyldiamine NH2(CH2)nNH2 (n=8; 10)

被引：12
作者：
Lu, SM
Ke, YX
Li, JM [1 ]
Zhou, SX
Wu, XT
Du, WX
机构：
[1] Univ Sci & Technol China, Dept Chem Phys, Anhua 230026, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
STRUCTURAL CHEMISTRY | 2003年 / 14卷 / 06期
基金：
中国国家自然科学基金;
关键词：
solvothermal synthesis; crystal structure; tin-selenide compound; two-dimensional complex; organic amine; ion exchange;
D O I：
10.1023/B:STUC.0000007574.13596.f6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of NH2(CH2)(n)NH2 (n = 8, 10) with elemental Sn and Se in a H2O/CH3OH mixture at 150degreesC afford two compounds (NH3(CH2)(8)NH3)Sn3Se7 (1) and (NH3(CH2)(8)NH3)Sn3Se (2). The crystal structures were determined by single crystal X-ray diffraction at room temperature. Both compounds exhibit the same anionic structure-a 6(3) netted plane composed of [Sn3Se7](2-) subunits. The distance between the centers of crystal 1 layers is 7.5 Angstrom, somewhat shorter than the distance (8.5 Angstrom) in crystal 2.
引用
收藏
页码：637 / 642
页数：6
相关论文
共 50 条
  • [1] Solvothermal Synthesis and Structure of Two 2D Tin–Selenides with Long Alkyldiamine NH2(CH2)nNH2 (n = 8, 10)
    Sheming Lu
    Yanxiong Ke
    Jianmin Li
    Shuxi Zhou
    Xintao Wu
    Wenxin Du
    Structural Chemistry, 2003, 14 : 637 - 642
  • [2] Solvothermal synthesis and crystal structure of [H2N(CH2)2NH3]{CO[H2N(CH2)2NH2]3}[SbSe4]
    Ming-Lai, F
    Chen, WT
    Cai, LZ
    Liu, B
    Guo, GC
    Huang, JS
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (07) : 731 - 734
  • [3] Solvothermal Synthesis and Crystal Structure of [H2N（CH2）2NH3]{Co[H2N（CH2）2NH2]3}[SbSe4]
    FU Ming-Lai a
    结构化学, 2004, (07) : 731 - 734
  • [4] Syntheses and Structures of Two New Borates: [NH3(CH2)3N(CH2)4N(CH2)3NH3][B5O6(OH)4]2 and [NH2(CH2)4N(CH2)2NH3][B7O10(OH)3]
    Wu, Lian-Zhi
    Cheng, Lin
    Yang, Guo-Yu
    JOURNAL OF CLUSTER SCIENCE, 2013, 24 (03) : 811 - 820
  • [5] Copper(I) nitrate π-complexation:: Synthesis and crystal structure of [{CH2=CH-CH2-NHC(NH2)2}Cu(NO3)2] compound
    Filinchuk, YE
    Mys'kiv, MG
    POLISH JOURNAL OF CHEMISTRY, 2000, 74 (07) : 927 - 933
  • [6] Synthesis, structure, lattice energy and enthalpy of 2D hybrid perovskite [NH3(CH2)4NH3]CoCl4, compared to [NH3(CH2)nNH3]CoCl4, n=3-9
    Abdel-Aal, Seham K.
    Abdel-Rahman, Ahmed S.
    JOURNAL OF CRYSTAL GROWTH, 2017, 457 : 282 - 288
  • [7] Solvothermal Synthesis and Characterization of (NH3CH2CH2NH3)HgSnS4 with a Column Structure
    WANG Yan-yan~ 1
    3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
    Chemical Research in Chinese Universities, 2006, (04) : 411 - 414
  • [8] Solvothermal synthesis and characterization of (NH3CH2CH2NH3) HgSnS4 with a column structure
    Wang Yan-yan
    Baiyin Meng-he
    Ji Shou-hua
    Liu Xiao-yang
    An Yong-lin
    Ning Gui-ling
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2006, 22 (04) : 411 - 414
  • [9] Synthesis and crystal structure of [U(η-C8H8)]2[μ-η4:η4-HN(CH2)3N(CH2)2N(CH2)3NH], a dinuclear compound with a bridging tetra-amide ligand
    Le Borgne, T
    Lance, M
    Nierlich, M
    Ephritikhine, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 598 (02) : 313 - 317
  • [10] Solvothermal synthesis and characterization of 1D (NH3CH2CH2NH3)AgASS4
    Li, XF
    Ji, M
    Baiyin, MH
    Jia, CY
    An, YL
    Wang, DH
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2004, 25 (03): : 409 - 412
12345