High-resolution photoabsorption cross-section measurements of SO2 at 198 K from 213 to 325 nm

被引:31
作者
Blackie, D. [1 ]
Blackwell-Whitehead, R. [2 ]
Stark, G. [4 ]
Pickering, J. C. [1 ]
Smith, P. L. [3 ]
Rufus, J. [1 ]
Thorne, A. P. [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Space & Atmospher Phys Grp, London SW7 2AZ, England
[2] Lund Observ, SE-22100 Lund, Sweden
[3] Harvard Smithsonian Ctr Astrophys, Cambridge, MA 02138 USA
[4] Wellesley Coll, Dept Phys, Wellesley, MA 02481 USA
关键词
FOURIER-TRANSFORM SPECTROMETER; JET-COOLED SO2; SULFUR-DIOXIDE; FLUORESCENCE SPECTROSCOPY; TEMPERATURE-DEPENDENCE; ABSORPTION-SPECTRUM; VENUS ATMOSPHERE; REGION; UV; ULTRAVIOLET;
D O I
10.1029/2010JE003707
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
SO2 plays an important role in the atmospheric chemistry of the Earth, Venus, and Io. This paper presents photoabsorption cross sections of SO2 from 213 to 325 nm at 198 K, encompassing the (C) over tilde B-1(2) - (X) over tilde (1)A(1) and (B) over tilde B-1(1) - (X) over tilde (1)A(1) electronic bands. These measurements are part of a series of measurements over the 160 to 300 K temperature range between 190 and 325 nm. The cross sections have been measured at high resolution (lambda/Delta lambda approximate to 450,000) using Fourier transform spectrometry and are compared to other high-resolution measurements in the literature.
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页数:8
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