Direct methylation and trifluoroethylation of imidazole and pyridine derivatives

被引:50
作者
Zhang, J [1 ]
Martin, GR [1 ]
DesMarteau, DD [1 ]
机构
[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
关键词
D O I
10.1039/b307230d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Direct methylation or trifluoroethylation of imidazole and pyridine derivatives using N-methyl bis((perfluoroalkyl)sulfonyl)imides or trifluoroethyl phenyliodonium bis((trifluoromethyl)sulfonyl)imide affords high yields of the corresponding salts. This methodology provides a simple route to a variety of room temperature ionic liquids (RTILs).
引用
收藏
页码:2334 / 2335
页数:2
相关论文
共 15 条
[1]   ELECTROCHEMICAL SCRUTINY OF ORGANOMETALLIC IRON COMPLEXES AND HEXAMETHYLBENZENE IN A ROOM-TEMPERATURE MOLTEN-SALT [J].
CHUM, HL ;
KOCH, VR ;
MILLER, LL ;
OSTERYOUNG, RA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (11) :3264-3265
[2]   The first fluoroalkylation of amino acids and peptides in water utilizing the novel iodonium salt (CF3SO2)2NI(Ph)CH2CF3 [J].
DesMarteau, DD ;
Montanari, V .
CHEMICAL COMMUNICATIONS, 1998, (20) :2241-2242
[3]   Easy preparation of bioactive peptides from the novel Nα-trifluoroethyl amino acids [J].
DesMarteau, DD ;
Montanari, V .
CHEMISTRY LETTERS, 2000, (09) :1052-1053
[4]   ELECTRODEPOSITION OF METALS FROM FUSED QUATERNARY AMMONIUM SALTS [J].
HURLEY, FH ;
WIER, TP .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1951, 98 (05) :203-206
[5]  
MacFarlane DR, 2000, ELECTROCHIM ACTA, V45, P1271
[6]   Pyrrolidinium imides: A new family of molten salts and conductive plastic crystal phases [J].
MacFarlane, DR ;
Meakin, P ;
Sun, J ;
Amini, N ;
Forsyth, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (20) :4164-4170
[7]  
Rogers R. D., 2002, ACS S SERIES, V818
[8]  
Rogers R. D., 2003, ACS S SERIES, V856
[9]   CHEMISTRY OF PERFLUOROMETHYLSULFONYL PERFLUOROBUTYLSULFONYL IMIDE [J].
SINGH, S ;
DESMARTEAU, DD .
INORGANIC CHEMISTRY, 1990, 29 (16) :2982-2985
[10]  
Wasserscheid P, 2000, ANGEW CHEM INT EDIT, V39, P3772, DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO