Synthesis of sulfur-containing polyfunctional terpenoids from (-)-carvone

被引：0

作者：

Bakopki, BN ^{[1
]}

Palei, RV ^{[1
]}

Plemenkov, VV ^{[1
]}

机构：

[1] Kazan State Med Univ, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2003年 / 73卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of (-)-carvone with aliphatic, aromatic, heterocyclic, and functional thiols, catalyzed with potassium carbonate, gave the corresponding derivatives in high yields. Isopropyl mercaptan, 2-mercapto-ethanol, furfuryl mercaptan, and N-acetylcysteine add across the endocyclic double bond of (-)-carvone with the predominant formation of the isomers with the S configuration of C-3, whereas addition of hexadecyl mercaptan and 1,2-ethanedithiol mainly yields the R isomers.

引用

页码：630 / 633

页数：4

共 6 条

[1] Stereospecific intramolecular Michael addition to (-)-carvone based on temporary sulfur connection [J].