Magnetism and Structure of a 3D Uncommon Pentanuclearcopper(II) Coordination Polymer

被引：1

作者：

Jin, J. C. ^{[1
]}

Zhong, H. R. ^{[2
,3
]}

Ma, A. Q. ^{[2
,3
]}

Huang, Y. J. ^{[2
,3
]}

Qiu, S. W. ^{[4
]}

Liu, J. Q. ^{[2
,3
]}

Luo, M. M. ^{[2
,3
]}

Xu, J. W. ^{[2
,3
]}

Wang, Y. Y. ^{[5
]}

Sakiyama, H. S. ^{[6
]}

机构：

[1] West Anhui Univ, Anhui Prov Lab Biomimet Sensor & Detecting Techno, Hefei 23701, Anhui, Peoples R China

[2] Guangdong Med Univ, Dongguan Key Lab Drug Design & Formulat Technol, Key Lab Res & Dev New Med Mat, Dongguan 523808, Peoples R China

[3] Guangdong Med Univ, Sch Pharm, Dongguan 523808, Peoples R China

[4] Guangdong Med Univ, Sch Inspect Sci, Dongguan 523808, Peoples R China

[5] Northwest Univ, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ,Coll Chem & Mat Sci, Xian 710069, Shaanxi, Peoples R China

[6] Yamagata Univ, Fac Sci, Dept Sci, Yamagata 9908560, Japan

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 44卷 / 11期

基金：

日本学术振兴会;

关键词：

tartaric acid; heteronuclear metal; magnetism; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; COMPLEXES; TRANSITION; MOLECULES; SOLIDS; DESIGN; CU(II); NETS;

D O I：

10.1134/S1070328418110039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D coordination polymer, [Na3KCu5(Tar)(2)(HTar)(2)(H2O)(7)] (I) (H(2)Tar = tartaric acid), was synthesized by the reaction of potassium sodium tartrate and Cu(NO3)(2) and characterized by X-ray single crystal diffraction (CIF file CCDC no. 1575976). Complex I is built up in a shell-like manner based on inner two symmetry-related pentanuclear copper cores, the cores are surrounded by coordinated synchronously Na and K atoms, which shapes into 3D nanoporous architecture. Additionally, I exhibits antiferromagnetic behavior.

引用

页码：693 / 700

页数：8

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