Magnetism and Structure of a 3D Uncommon Pentanuclearcopper(II) Coordination Polymer

被引：1

作者：

Jin, J. C. ^{[1
]}

Zhong, H. R. ^{[2
,3
]}

Ma, A. Q. ^{[2
,3
]}

Huang, Y. J. ^{[2
,3
]}

Qiu, S. W. ^{[4
]}

Liu, J. Q. ^{[2
,3
]}

Luo, M. M. ^{[2
,3
]}

Xu, J. W. ^{[2
,3
]}

Wang, Y. Y. ^{[5
]}

Sakiyama, H. S. ^{[6
]}

机构：

[1] West Anhui Univ, Anhui Prov Lab Biomimet Sensor & Detecting Techno, Hefei 23701, Anhui, Peoples R China

[2] Guangdong Med Univ, Dongguan Key Lab Drug Design & Formulat Technol, Key Lab Res & Dev New Med Mat, Dongguan 523808, Peoples R China

[3] Guangdong Med Univ, Sch Pharm, Dongguan 523808, Peoples R China

[4] Guangdong Med Univ, Sch Inspect Sci, Dongguan 523808, Peoples R China

[5] Northwest Univ, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ,Coll Chem & Mat Sci, Xian 710069, Shaanxi, Peoples R China

[6] Yamagata Univ, Fac Sci, Dept Sci, Yamagata 9908560, Japan

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 44卷 / 11期

基金：

日本学术振兴会;

关键词：

tartaric acid; heteronuclear metal; magnetism; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; COMPLEXES; TRANSITION; MOLECULES; SOLIDS; DESIGN; CU(II); NETS;

D O I：

10.1134/S1070328418110039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D coordination polymer, [Na3KCu5(Tar)(2)(HTar)(2)(H2O)(7)] (I) (H(2)Tar = tartaric acid), was synthesized by the reaction of potassium sodium tartrate and Cu(NO3)(2) and characterized by X-ray single crystal diffraction (CIF file CCDC no. 1575976). Complex I is built up in a shell-like manner based on inner two symmetry-related pentanuclear copper cores, the cores are surrounded by coordinated synchronously Na and K atoms, which shapes into 3D nanoporous architecture. Additionally, I exhibits antiferromagnetic behavior.

引用

页码：693 / 700

页数：8

共 50 条

[31] Synthesis, Crystal Structure and Thermal Stability of 1D Copper(II) Coordination Polymer [J].

Xu Jing ;

Deng Zhao-Peng ;

Huo Li-Hua ;

Gao Shan .

CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (09) :1748-1752

[32] Synthesis and Crystal Structure of Iron(II) Coordination Polymer Composed of 1D Chains [J].

Che Guang-Bo ;

Li Xiu-Ying ;

Xu Zhan-Lin ;

Liu Chun-Bo ;

Wang Qing-Wei .

CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (03) :556-559

[33] Ionothermal Synthesis of a 3D Luminescent Strontium(II) Coordination Polymer with Dodecanuclear Metallocyclic Ring Segments [J].

Liu, Shun-Shun ;

Cheng, Meng ;

Li, Bing ;

Shi, Wen-Hui ;

Bai, Yan ;

Dang, Dong-Bin .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2015, 25 (05) :1103-1110

[34] A 3D chiral Co(II) coordination polymer featuring unique self-interpenetrating topology [J].

Wang, Xiao-Fang ;

Liu, Yang .

INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 27 :76-78

[35] A 3D Cu(II) tetrazolate coordination polymer based on pentanuclear units with a large coercive field [J].

Sun, Wu-Juan ;

Li, Lei-Lei ;

Liu, Xiang-Yu ;

Liu, Shuang ;

Ke, Cong-Yu ;

Zhang, Qun-Zheng ;

Zhang, Xun-Li .

DALTON TRANSACTIONS, 2020, 49 (03) :651-658

[36] A Novel 3D Cd(II) Coordination Polymer with an Unusual 3-Connected (82.10) Lig Net: Synthesis, Crystal Structure and Luminescent Properties [J].

Wang Ji-Wu ;

Wang Hai-Bing ;

Wang Zi ;

Tang Ping ;

Wu Ya-Pan .

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (12) :1843-1848

[37] Synthesis, Structure and Photoelectric Property of a 3D Supramolecular Zinc Coordination Polymer [J].

Luo Ya-Nan ;

Liu Zhi-Chen ;

Jiang Hui-Yang ;

Yu Li-Yang ;

Yu Xiao-Yang .

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37 (03) :421-426

[38] Synthesis, crystal structure, and photoelectrical property of a new (3,6) connected 3D Zn(II) coordination polymer [J].

Luo, Yanan ;

Jiang, Huiying ;

Yu, Liying ;

Liu, Zhichen ;

Yu, Xiaoyang .

INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 86 :304-307

[39] Hydrothermal Synthesis and Crystal Structure of a New 2D Zinc(II) Coordination Polymer with 2-Aminoethanesulfonic Acid [J].

Cai Jin-Hua ;

Zhong Fan ;

Jiang Yi-Min .

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 30 (05) :743-747

[40] Synthesis, Structure, and Luminescence of a New 3D Heterometallic Coordination Polymer Constructed by 2-Hydroxynicotinate [J].

Xu, Zhan-Lin ;

Liu, Fu-Yi ;

Zhang, Yuan-Yuan .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (10) :1504-1508

← 1 2 3 4 5 →