Mercury(II)-carbon bond cleavage due to the coordination of the metal by 2-(2'-pyridyl)quinoxaline (L): Preparation and characterization of [Hg(2)I(4)L(2)] derived from the reaction of CH3HgI and L

被引：26

作者：

Garoufis, A

Perlepes, SP

Schreiber, A

Bau, R

Hadjiliadis, N

机构：

[1] UNIV IOANNINA,DEPT CHEM,INORGAN & GEN CHEM LAB,GR-45110 IOANNINA,GREECE

[2] TECHNOL INST ATHENS,DEPT CHEM PHYS & MAT TECHNOL,ATHENS,GREECE

[3] UNIV PATRAS,DEPT CHEM,GR-26500 PATRAI,GREECE

[4] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089

来源：

POLYHEDRON | 1996年 / 15卷 / 02期

关键词：

D O I：

10.1016/0277-5387(95)00259-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 2:1 and 1:1 reactions of MeHgI with 2-(2'-pyridyl)quinoxaline (L) in methanol led to Hg-C bond cleavage and yielded the dinuclear complex [Hg(2)I(4)L(2)] as one of the products. The crystal structure of this compound shows a chelating behaviour of L and different (terminal, asymmetric bridging) iodide coordination modes. Some spectroscopic characteristics of the dimer and the biological relevance of this reaction are also reported.

引用

页码：177 / 182

页数：6

共 24 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].