Optical properties of Eu3+ :CsGd2F7 downconversion phosphor

被引:19
作者
Karbowiak, M
Mech, A
Ryba-Romanowski, W
机构
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
[2] Polish Acad Sci, W Trzebiatowski Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland
关键词
downconversion; quantum cutting; vacuuni ultraviolet; phosphor; CsGd2F7;
D O I
10.1016/j.jlumin.2004.12.004
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Luminescence spectra and excitation spectra in 150-420 nm spectral region have been recorded at room temperature for polycrystalline sample of (0.5%)Eu3+:CsGd2F7. The relatively intense emission has been observed from D-5(3), D-5(2), and D-5(1) levels. Emission and excitation spectra prove that the excitation energy is efficiently transferred from the (6)G(J) and I-6(j) levels of Gd3+ ions to Eu3+ ions. The visible quantum cutting via downconversion has been detected, with efficiency of the cross-relaxation step of similar to 50%. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:65 / 70
页数:6
相关论文
共 20 条
[1]   CRYSTAL-STRUCTURE OF B-PHASE-KER2F7 - ISOTYPIC COMPOSITION [J].
ALEONARD, S ;
LEFUR, Y ;
GORIUS, MF ;
ROUX, MT .
JOURNAL OF SOLID STATE CHEMISTRY, 1980, 34 (01) :79-89
[2]   Luminescence of CsGd2F7: Er3+, Dy3+ under VUV excitation [J].
Belsky, AN ;
Khaidukov, NM ;
Krupa, JC ;
Makhov, VN ;
Philippov, A .
JOURNAL OF LUMINESCENCE, 2001, 94 :45-49
[3]   Optical spectroscopy of Nd3+ ions in CsGd2F7 host [J].
de Barros, CLM ;
Barthem, RB ;
Khaidukov, NM .
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 142 (01) :108-112
[4]   Optical excitation of Nd3+ pairs in CsGd2F7 crystals [J].
de Barros, CLM ;
Barthem, RB ;
Khaidukov, NM .
JOURNAL OF LUMINESCENCE, 1999, 82 (04) :307-314
[5]  
DEKOZAK A, 1977, REV CHIM MINER, V14, P93
[6]   UV and VUV optical excitations in wide band gap materials doped with rare earth ions: 4f-5d transitions [J].
Krupa, JC ;
Queffelec, M .
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 250 (1-2) :287-292
[7]   Spectroscopic properties of Pr3+ luminescence in complex fluoride crystals [J].
Makhov, VN ;
Khaidukov, NM ;
Lo, D ;
Kirm, M ;
Zimmerer, G .
JOURNAL OF LUMINESCENCE, 2003, 102 :638-643
[8]   CALCULATED QUANTUM YIELDS FOR PHOTON-CASCADE EMISSION (PCE) FOR PR-3+ AND TM-3+ IN FLUORIDE HOSTS [J].
PAPPALARDO, R .
JOURNAL OF LUMINESCENCE, 1976, 14 (03) :159-193
[9]  
Piper W. W., 1974, Journal of Luminescence, V8, P344, DOI 10.1016/0022-2313(74)90007-6
[10]   PHOSPHORS FOR LAMPS AND DISPLAYS - AN APPLICATIONAL VIEW [J].
RONDA, CR .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 225 (1-2) :534-538