Synthesis and spectral studies of class I mixed valence binuclear copper(II)-copper(I) complexes

被引：0

作者：

Patel, R. N. ^{[1
]}

机构：

[1] APS Univ, Dept Chem, Rewa 486003, India

来源：

OXIDATION COMMUNICATIONS | 2007年 / 30卷 / 03期

关键词：

mixed valence copper(II)-copper(I) complexes; electronic structure; electron paramagnetic resonance;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of new mixed valence binuclear copper(Il)-copper(l) complexes, viz. [(DAPDH(2))CuCl2] (1), [(DAPDH(2))CuCl2CuCI] (2), [(DAPDH(2))CUCl2CuI] (3) and [(DAPDH(2))CUCl2CuSCN] (4) where DAPDH(2) = 2,6-diacetylpyridine dioxime were synthesised and characterised by means of elemental analysis, magnetic susceptibility and spectroscopic techniques. The Cu(I)X (where X = Cl, 1, SCN) and [(DAPDH(2))CUCl2] (1) are attached via two bridging chlorine atoms. UV-vis. and electron paramagnetic resonance (EPR) spectroscopic studies established the presence of significant perturbation of the Cu(I)X unit to the electronic structure of the copper(II) ion in [(DAPDH(2))CUCl2] (1).

引用

页码：524 / 528

页数：5

共 11 条

[1]

[Anonymous], 1977, PHYS METHODS CHEM

[2] NICKEL(II) AND NICKEL(IV) COMPLEXES OF 2,6-DIACETYLPYRIDINE DIOXIME [J].