Synthesis, characterization, and structural study of K2FeZrP3O12 with the langbeinite structure

被引：37

作者：

Orlova, AI

Trubach, IG

Kurazhkovskaya, VS

Pertierra, P

Salvadó, MA

García-Granda, S

Khainakov, SA

García, JR ^{[1
]}

机构：

[1] Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan, E-33006 Oviedo, Spain

[2] Nizhni Novgorod State Univ, Dept Chem, Nizhnii Novgorod 603950, Russia

[3] Moscow MV Lomonosov State Univ, Dept Geol, Moscow 119899, Russia

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2003年 / 173卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1016/S0022-4596(03)00101-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A potassium iron zirconium phosphate, K2FeZrP3O12, was synthesized by thermal treatment of a material obtained by the sol-gel method, mixing two aqueous solutions, the first containing KCl, FeCl3 and ZrOCl2, and the second, H3PO4. The crystal structure was refined using powder X-ray diffraction data. The unit cell is cubic, a = 10.0554(3) Angstrom, space group P2(1)3. This compound is the first iron zirconium phosphate described with a langbeinite-type structure. (C) 2003 Elsevier Science (USA). All rights reserved.

引用

页码：314 / 318

页数：5

共 34 条

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[Anonymous], 1986, New directions in solid state chemistry

[2] THE MAGNETIC-PROPERTIES OF THE SYNTHETIC LANGBEINITE KBACR2(PO4)3 [J].