A biodegradable polymer-assisted efficient and universal exfoliation route to a stable few layer dispersion of transition metal dichalcogenides

被引:8
作者
Yadav, Priyanka [1 ]
Das, Anirban [1 ,3 ]
Sharma, Manoj Kumar [1 ]
Ash, Soumen [1 ]
Ganguli, Ashok Kumar [1 ,2 ]
机构
[1] Indian Inst Technol Delhi, Dept Chem, New Delhi 110016, India
[2] Indian Inst Technol Delhi, Dept Mat Sci & Engn, New Delhi 110016, India
[3] Amity Univ Haryana, Amity Sch Appl Sci, Dept Chem Biochem & Forens Sci, Gurgaon 122413, Haryana, India
关键词
2D material; Quasi 2D transition metal dichalcogenides (TMDCs); Ultrasonication; MoS2; NbS2; LIQUID-PHASE EXFOLIATION; MOS2; NANOSHEETS; DISULFIDE; MONOLAYER; CRYSTALS; BULK;
D O I
10.1016/j.matchemphys.2021.125347
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Quasi two-dimensional transition metal dichalcogenides (2D-TMDs) with 1-5 layers have been obtained by developing an effective and highly efficient bio-based polymer-solvent system by mild ultrasonication. The hydroxypropyl cellulose (HPC)/1-Butanol (BuOH) system was determined to be an universal polymer-solvent system to effectively exfoliate the bulk transition metal dichalcogenides (TMDs) MoS2, TiS2, WS2, NbS2 and MoSe2. The above process is significant as it is a room temperature liquid phase exfoliation method that leads to a stable dispersion of a few layer 2D-TMD having significant proportion (>50%) of exfoliated material which remains stable in suspension for several months.
引用
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页数:9
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