High-Tg Transparent Poly(ether sulfone)s Based on Phosphinated Bisphenols

被引：14
|
作者：
Lin, Ching Hsuan [1 ]
Chang, Sheng Lung [1 ]
Wei, Tsai Pei [1 ]
机构：
[1] Natl Chung Hsing Univ, Dept Chem Engn, Taichung 40227, Taiwan
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 2011年 / 212卷 / 05期
关键词：
DOPO; epoxies; flame retardants; low water absorption; polyimides; DECKER-SHAPED SILSESQUIOXANE; SOLUBLE POLYIMIDES; MAIN-CHAIN; HIGH ORGANOSOLUBILITY; CARDO POLYAMIDES; IMIDE)S; POLYSULFONE; PHOSPHORUS; UNITS; DIANHYDRIDES;
D O I：
10.1002/macp.201000505
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The preparation of high-T-g transparent polymers from poly(ether sulfone)s with bulky phosphinate pendants is described. Poly(ether sulfone) s P1-P3 based on biphenylene phosphinate-substituted bisphenols were prepared. The thermal properties of P1 and P2 were studied and compared with a bisphenol-A-based poly(ether sulfone). P1 and P2 are flexible, foldable, and highly transparent with a cutoff wavelength around 327 and 328 nm, respectively. They display higher glass transition temperature (258 and 274 degrees C) and lower coefficient of thermal expansion (delta = 48 ppm per degrees C by TMA) than those of P0 (208 degrees C and delta = 57 ppm per degrees C).
引用
收藏
页码：455 / 464
页数：10
相关论文
共 50 条
  • [1] Design and synthesis of unsymmetric phosphinated diamines for high-Tg, transparent polyimides
    Chang, Hou Chien
    Chang, Sheng Lung
    Lin, Ching Hsuan
    Chen, Sinn Wen
    POLYMER, 2012, 53 (08) : 1651 - 1658
  • [2] Soluble High-Tg Polyetherimides with Good Flame Retardancy Based on an Asymmetric Phosphinated Etherdiamine
    Lin, Ching Hsuan
    Chang, Sheng Lung
    Cheng, Po Wen
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (06) : 1331 - 1340
  • [3] Poly(ether ether sulfone)s and sulfonated poly(ether ether sulfone)s derived from functionalized 1,1-diphenylethylene derivatives
    Summers, Gabriel J.
    Kasiama, M. Ginette
    Summers, Carol A.
    POLYMER INTERNATIONAL, 2016, 65 (07) : 798 - 810
  • [4] Novel high performance poly(sulfone-ether-amide-imide)s
    Nazemzadeh, Sajjad
    Mehdipour-Ataei, Shahram
    INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION, 2022, 27 (04) : 252 - 265
  • [5] New fluorinated poly(ether sulfone imide)s with high thermal stability and low dielectric constant
    Wang, Chenyi
    Chen, Wentao
    Chen, Yunyun
    Zhao, Xiaoyan
    Li, Jian
    Ren, Qiang
    MATERIALS CHEMISTRY AND PHYSICS, 2014, 143 (02) : 773 - 778
  • [6] Triptycene poly(ether-imide)s with high solubility and optical transparency
    Hsiao, Sheng-Huei
    Wang, Hui-Min
    Chou, Ji-Shian
    Guo, Wenjeng
    Lee, Tzong-Ming
    Leu, Chyi-Ming
    Su, Chun-Wei
    JOURNAL OF POLYMER RESEARCH, 2012, 19 (01)
  • [7] Poly(ether ether sulfone amide)s as a new category of processable heat-resistant polymers
    Khademinejad, Saeed
    Mehdipour-Ataei, Shahram
    Ziaee, Farshid
    Abbasi, Farideh
    DESIGNED MONOMERS AND POLYMERS, 2016, 19 (06) : 553 - 559
  • [8] Novel Ferrocene-Based Organometallic Poly(ether sulfone amide imide)s: Preparation, Characterization, and Properties
    Ebadi-Dehaghani, Hassan
    Mehdipour-Ataei, Shahram
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2012, 22 (01) : 223 - 234
  • [9] Electron-withdrawing/donating effects of substituents on the preparation of phosphinated 4,4′-diaminodiphenylmethane for soluble, anti-oxidative, and high-Tg polyimides
    Lin, Ching Hsuan
    Chang, Sheng Lung
    Fang, Yu Ting
    Chou, Ming Hsien
    HIGH PERFORMANCE POLYMERS, 2012, 24 (02) : 140 - 149
  • [10] High-Performance Thermosetting Films Based on an Amino-Functionalized Poly(ether sulfone)
    Lin, Ching Hsuan
    Chen, Jui Chun
    Huang, Chu Ming
    Juang, Tzong Yuan
    JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (21)
12345