2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(I)

被引：28

作者：

Campos Carrasco, Ariadna ^{[2
]}

Pidko, Evgeny A. ^{[1
]}

Masdeu-Bulto, Anna M. ^{[2
]}

Lutz, Martin ^{[3
]}

Spek, Anthony L. ^{[3
]}

Vogt, Dieter ^{[1
]}

Muller, Christian ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Dept Chem Engn & Chem, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

[2] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain

[3] Univ Utrecht, Dept Crystal & Struct Chem, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

NEW JOURNAL OF CHEMISTRY | 2010年 / 34卷 / 08期

关键词：

RAY CRYSTAL-STRUCTURE; PYRYLIUM-SALTS; COMPLEXES; LIGANDS; PHOSPHININES; POLYDENTATE; PHOSPHORUS; REACTIVITY; NIPHOS; RH;

D O I：

10.1039/c0nj00030b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination chemistry of the bidentate P,N hybrid ligand 2-(2'-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2'-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L-2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to pyridines.

引用

页码：1547 / 1550

页数：4

共 30 条

[1] SYNTHESIS OF 2-(2'-PYRIDYL)PHOSPHORIN [J].

ALCARAZ, JM ;

BREQUE, A ;

MATHEY, F .

TETRAHEDRON LETTERS, 1982, 23 (15) :1565-1568

[2]

Breit B, 2001, CHEM-EUR J, V7, P3106, DOI 10.1002/1521-3765(20010716)7:14<3106::AID-CHEM3106>3.0.CO

[3]

2-Y

[4] 4,5-DIMETHYL-2-(2-PYRIDYL)PHOSPHORIN AS A CHELATING LIGAND - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE ANALYSIS OF (4,5-DIMETHYL-2-(2-PYRIDYL)PHOSPHORIN)TETRACARBONYLCHROMIUM [J].

BREQUE, A ;

SANTINI, CC ;

MATHEY, F ;

FISCHER, J ;

MITSCHLER, A .

INORGANIC CHEMISTRY, 1984, 23 (22) :3463-3467

[5] Efficient synthesis of pyridines via a sequential solventless aldol condensation and Michael addition [J].

Cave, GWV ;

Raston, CL .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2001, (24) :3258-3264

[6]

CHRISHOLM MH, 1981, J AM CHEM SOC, V103, P4945

[7]

Doux M, 2003, EUR J INORG CHEM, P687

[8]

Felix A, 1999, Z KRIST-NEW CRYST ST, V214, P463

[9]

Frisch M., 2004, GAUSSIAN 03 REVISION, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014

[10] Bipyridine:: The most widely used ligand.: A review of molecules comprising at least two 2,2′-bipyridine units [J].

Kaes, C ;

Katz, A ;

Hosseini, MW .

CHEMICAL REVIEWS, 2000, 100 (10) :3553-3590

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