Robust Porphyrin-Spaced Zirconium Pyrogallate Frameworks with High Proton Conduction

被引：32

作者：

Chen, Er-Xia ^{[1
,2
]}

Xu, Gang ^{[1
]}

Lin, Qipu ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

INORGANIC CHEMISTRY | 2019年 / 58卷 / 06期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; DESIGN; TRANSPORT;

D O I：

10.1021/acs.inorgchem.8b03132

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An isoreticular family of zirconium poly phenolate networks (ZrPP-n, n = 1 and 2), bridged by porphyrinic macrocycles in an eclipsed arrangement, have excellent stability toward water, especially strong basic media of saturated NaOH aqueous solution. Endowed with spatial alignment of protic sites, viz., partially protonated phenols of acidity enhanced by coordination to Zr4+, along with guest dimethylamine cations, the newly synthesized ZrPP-n reveal exceptional conductivity (8.0 X 10(-3) and 4.2 X 10(-3) S cm(-1), for n = 1 and 2, respectively, pelleted sample, under 98% relative humidity at 25 degrees C).

引用

页码：3569 / 3573

页数：5

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