Synergistic Ag(I)/nBu4NBr-catalyzed fixation of CO2 to β-oxopropyl carbonates via propargylic alcohols and monohydric alcohols

被引：10

作者：

Li, Jingyuan ^{[1
]}

Song, Qingwen ^{[2
]}

Zhang, Hengxuan ^{[3
]}

Liu, Ping ^{[2
]}

Zhang, Kan ^{[2
]}

Wang, Junwen ^{[3
]}

Zhang, Dengsong ^{[1
]}

机构：

[1] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China

[2] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China

[3] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Shanxi, Peoples R China

来源：

TETRAHEDRON | 2019年 / 75卷 / 15期

基金：

中国国家自然科学基金;

关键词：

Carbon dioxide utilization; beta-Oxoalkyl carbonates; Cascade reaction; Synergistic catalysis; Synthetic methods; ALKYLIDENE CYCLIC CARBONATES; EFFICIENT SYNTHESIS; SELECTIVE SYNTHESIS; ORGANIC CARBONATES; AMBIENT CONDITIONS; CATALYTIC-SYSTEM; DIOXIDE; SULFADIAZINE; TRANSFORMATION; DERIVATIVES;

D O I：

10.1016/j.tet.2019.03.006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chemical fixation of carbon dioxide under mild reaction conditions e.g. atmospheric pressure and low temperature depends upon the ability of catalyst. Herein, a synergistic catalytic scheme of silver sulfadiazine/(Bu4NBr)-Bu-n was described for the three-component reaction of propargylic alcohols, CO2, and monohydric alcohols. This catalytic system was demonstrated effectively to provide beta-oxopropyl carbonates in excellent yields (up to 99% yield with 5 mol% catalyst). The method tolerated a wide scope of propargylic alcohols and monohydric alcohols under atmospheric CO2 pressure and solvent-free conditions. The excellent catalytic performance was attributed to the synergistic catalysis confirmed by the careful experiments. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页码：2343 / 2349

页数：7

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