Selective sorption and preconcentration of tartaric acid using a copper(II)-bound polymeric ligand exchanger

被引:6
作者
Du, Wei [1 ]
Pan, Bingcai [1 ]
Jiang, Peijuan [1 ]
Zhang, Qingrui [1 ]
Zhang, Weiming [1 ]
Pan, Bingjun [1 ]
Zhang, Qingjian [1 ]
Zhang, Quanxing [1 ]
机构
[1] Nanjing Univ, Sch Environm, State Key Lab Pollut Control & Resource Reuse, Nanjing 210093, Peoples R China
关键词
tartaric acid; selective sorption; preconcentration; polymeric ligand exchanger; Cu(II);
D O I
10.1016/j.cej.2007.07.098
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The current study reports a potential process to selectively separate and preconcentrate tartaric acid from its simulated industrial effluent. It was achieved by sorption onto a tailored polymeric ligand exchanger. The polymeric ligand exchanger is essentially a copper(II)-bound specialty chelating polymer (denoted D-Cu). Effect of solution pH and competing sulfate on tartaric acid sorption onto D-Cu was also included in the study. Compared to a weakly basic anion exchanger D-301, D-Cu exhibits more favorable sorption of tartaric acid from aqueous media coexisting with Na2SO4 at a high level. The exhausted D-Cu was amenable to an entire regeneration by the diluted NaCl solution. Results of column sorption tests further demonstrated the feasibility of D-Cu for selective separation and preconcentration of tartaric acid from the simulated wastewater for its further recovery. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:63 / 68
页数:6
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