Linear dimerisation of but-1-ene in biphasic mode using buffered chloroaluminate ionic liquid solvents

被引：173

作者：

Ellis, B

Keim, W

Wasserscheid, P

机构：

[1] Rhein Westfal TH Aachen, Inst Tech Chem & Petrolchem, D-52074 Aachen, Germany

[2] BP Chem, Sunbury On Thames TW16 7LN, Middx, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 04期

关键词：

D O I：

10.1039/a808346k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of a buffered ionic liquid as a solvent for catalysts known to produce linear dimers from but-1-ene has been explored; this resulted in a significant enhancement of the activity of known catalysts, combined with the retention of both dimer selectivity and product linearity; in addition, the biphasic mode of operation allows easy catalyst recovery and recycle.

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收藏

页码：337 / 338

页数：2

相关论文

共 13 条

[1] CATALYTIC DIMERIZATION OF ALKENES BY NICKEL-COMPLEXES IN ORGANOCHLOROALUMINATE MOLTEN-SALTS [J].

CHAUVIN, Y ;

GILBERT, B ;

GUIBARD, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (23) :1715-1716

[2] Oligomerization of n-butenes catalyzed by nickel complexes dissolved in organochloroaluminate ionic liquids [J].

Chauvin, Y ;

Olivier, H ;

Wyrvalski, CN ;

Simon, LC ;

deSouza, RF .

JOURNAL OF CATALYSIS, 1997, 165 (02) :275-278

[3] CATALYTIC DIMERIZATION OF PROPENE BY NICKEL-PHOSPHINE COMPLEXES IN 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE/ALETXCL3-X (X=0,1) IONIC LIQUIDS [J].

CHAUVIN, Y ;

EINLOFT, S ;

OLIVIER, H .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (04) :1149-1155

[4]

Chauvin Y., 1995, ANGEW CHEM, V107, P2941

[5] ELECTROCHEMICAL SCRUTINY OF ORGANOMETALLIC IRON COMPLEXES AND HEXAMETHYLBENZENE IN A ROOM-TEMPERATURE MOLTEN-SALT [J].

CHUM, HL ;

KOCH, VR ;

MILLER, LL ;

OSTERYOUNG, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (11) :3264-3265

[6]

EINLOFT S, 1996, Patent No. 5550304

[7] LINEAR OLIGOMERIZATION OF OLEFINS VIA NICKEL CHELATE COMPLEXES AND MECHANISTIC CONSIDERATIONS BASED ON SEMIEMPIRICAL CALCULATIONS [J].

KEIM, W ;

HOFFMANN, B ;

LODEWICK, R ;

PEUCKERT, M ;

SCHMITT, G ;

FLEISCHHAUER, J ;

MEIER, U .

JOURNAL OF MOLECULAR CATALYSIS, 1979, 6 (02) :79-97

[8] ELECTROCHEMICAL STUDIES OF SODIUM-CHLORIDE AS A LEWIS BUFFER FOR ROOM-TEMPERATURE CHLOROALUMINATE MOLTEN-SALTS [J].

MELTON, TJ ;

JOYCE, J ;

MALOY, JT ;

BOON, JA ;

WILKES, JS .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (12) :3865-3869

[9] STOICHIOMETRY OF LATENT ACIDITY IN BUFFERED CHLOROALUMINATE IONIC LIQUIDS [J].

QUARMBY, IC ;

MANTZ, RA ;

GOLDENBERG, LM ;

OSTERYOUNG, RA .

ANALYTICAL CHEMISTRY, 1994, 66 (21) :3558-3561

[10] LATENT ACIDITY IN BUFFERED CHLORALUMINATE IONIC LIQUIDS [J].

QUARMBY, IC ;

OSTERYOUNG, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (06) :2649-2650