Host-guest complexes of local anesthetics with cucurbit[6]uril and para-sulphonatocalix[8]arene in the solid state

被引：9

作者：

Danylyuk, Oksana ^{[1
]}

Butkiewicz, Helena ^{[1
]}

Coleman, Anthony W. ^{[2
]}

Suwinska, Kinga ^{[3
,4
]}

机构：

[1] Polish Acad Sci, Inst Phys Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland

[2] Univ Lyon 1, LMI, CNRS UMR 5615, 43 Bvd 11 Novembre, F-69622 Villeurbanne, France

[3] Cardinal Stefan Wyszynski Univ, Fac Math & Nat Sci, Woycickiego 1-3, PL-01938 Warsaw, Poland

[4] Kazan Fed Univ, AM Butlerov Inst Chem, Kremlevskaya 18, Kazan 420008, Russia

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1150卷

关键词：

Host-guest complex; Crystal structure; Cucurbit[6]uril; p-sulphonatocalix[8]arene; Anesthetic drug; P-SULFONIC ACID; BETA-CYCLODEXTRIN; SUPRAMOLECULAR ASSEMBLIES; INCLUSION COMPLEXATION; COORDINATION POLYMERS; CUCURBITURIL; TETRACAINE; MOLECULES; CRYSTALLIZATION; OPPORTUNITIES;

D O I：

10.1016/j.molstruc.2017.08.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Here we describe the host-guest inclusion complexes of local anesthetic drugs with two macrocyclic hosts cucurbit[6]uril and para-sulphonatocalix[8]arene in the solid state. The anesthetic agents used in the co-crystallization with the supramolecular hosts are lidocaine, procaine, procainamide, prilocaine and proparacaine. Both macrocycles encapsulate the alkylammonium moieties of anestetics guests into their cavities although the mechanism of complexation, host-guest stoichiometry and geometry differ depending on the nature of the supramolecular host. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：28 / 36

页数：9

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