A simple and rapid method for determination of boron in fast breeder reactor components

被引：4

作者：

Gupta, S. N. V. M. S. ^{[1
]}

Nayak, A. K. ^{[1
]}

Misra, U. B. ^{[1
]}

Yarasi, Balaji Rao ^{[1
]}

Babu, C. Phani ^{[1
]}

Kalyanakrishnan, G. ^{[1
]}

机构：

[1] Nucl Fuel Complex, Control Lab, Hyderabad 500062, Andhra Pradesh, India

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2017年 / 313卷 / 03期

关键词：

Boron; Radio frequency glow discharge optical emission spectrometer; Steel; Fast breeder reactor; Inter element interference; EMISSION-SPECTROMETRIC DETERMINATION; BORATE;

D O I：

10.1007/s10967-017-5372-1

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The present paper describes a new analytical method developed for direct determination of boron in steels using radio frequency glow discharge optical emission spectrometer. "Single parameter alternative method" technique has been used to optimize the various experimental conditions of glow discharge plasma such as forward power, gas pressure inside plasma chamber, pre-integration time, and integration time. Different emission lines for boron were studied and inter element interference effect is also discussed in the paper. A complete statistical analysis has been done to validate the developed method. A RSD of less than +/- 5% is achieved for boron in the range of 0.0010-0.020% in Steels using this method.

引用

页码：571 / 579

页数：9

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