Influence of coating on the photoluminescence of Tb3+ doped ZnSe/ZnS core-shell quantum dots

被引:11
作者
Cichos, J. [1 ]
Karbowiak, M. [1 ]
Hreniak, D. [2 ]
Strek, W. [2 ]
机构
[1] Univ Wroclaw, Fac Chem, Ul F Joliot Curie 14, PL-50383 Wroclaw, Poland
[2] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50422 Wroclaw, Poland
关键词
quantum dots; lanthanide; ZnSe; terbium; rare earths; NANOCRYSTALS; LUMINESCENCE; LANTHANIDES; YB3+;
D O I
10.1016/S1002-0721(16)60101-1
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Tb3+-doped ZnSe and ZnSe/ZnS nanocrystals were synthesized using modified hot-injection method. The observation of the characteristic quantum dots absorption features in a time-gated excitation spectrum was recorded while monitoring Tb3+ emission at 545 nm provided direct evidence for successful incorporation of dopant ions into semiconductor host. Relatively long decay time (similar to 1.5 ms) of Tb3+ emission indicated that dopant ions were well protected from interaction with surface ligands. Emission properties of core ZnSe: Tb3+ nanocrystals were only slightly modified upon growth of ZnS shell.
引用
收藏
页码:828 / 832
页数:5
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