Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to Quinone Monoketals

被引：4
|
作者：
Sun, Guijiu [1 ]
Xiao, Fanhua [1 ]
Duan, Weiliang [2 ]
机构：
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China
[2] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 40卷 / 01期
基金：
中国国家自然科学基金;
关键词：
palladium catalysis; diarylphosphine; asymmetric addition; BAYLIS-HILLMAN CARBONATES; P-STEREOGENIC PHOSPHINES; PCN PINCER PALLADIUM(II); ENANTIOSELECTIVE HYDROPHOSPHINATION; ACTIVATED OLEFINS; MICHAEL ADDITION; OXIDES; ENONES; DIPHENYLPHOSPHINE; PHOSPHORUS;
D O I：
10.6023/cjoc201905022
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An asymmetric 1,4-addition reaction of diarylphosphines with quinone monoketals was studied. Pincer Pd complex was used as catalyst to generate a series of chiral phosphorus compounds with moderate to good enantioselectivities in high yields.
引用
收藏
页码：61 / 68
页数：8
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