Thermodynamic determination of the cation distribution in NixMn1-γ-xFe2+γO4 ferrites

被引：5

作者：

Wei, QM ^{[1
]}

Robertson, BW

机构：

[1] Univ Nebraska, Dept Mech Engn, Lincoln, NE 68588 USA

[2] Univ Nebraska, Ctr Mat Res & Anal, Lincoln, NE 68588 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2003年 / 176卷 / 01期

关键词：

thermodynamics; cation distribution; ferrite;

D O I：

10.1016/S0022-4596(03)00382-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cation distribution in the spinel ferrite system Ni(x)Mn(1-y-x)Fe(2+y)O4 (x = 0, 0.25, 0.5, 0.75 and y = 0.137) has been calculated analytically in complete form as a function of thermodynamic parameters. A generalized theoretical framework based on the O'Neill-Navrotsky model and Newton methods was used to solve a multicomponent system for up to 10 cation species. The relationship between the cation distribution and composition is given. The results are shown to agree with the available experimental results. (C) 2003 Elsevier Inc. All rights reserved.

引用

收藏

页码：279 / 283

页数：5

相关论文

共 12 条

[1] ELECTRICAL-PROPERTIES AND SITE DISTRIBUTION OF CATIONS IN (MNYCO1-Y)0.4FE2.6O4 [J].

CARTER, DC ;

MASON, TO .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1988, 71 (04) :213-218

[2] ELECTRONIC PROPERTIES OF TRANSITION-METAL OXIDES .2. CATION DISTRIBUTION AMONGST OCTAHEDRAL AND TETRAHEDRAL SITES [J].

DUNITZ, JD ;

ORGEL, LE .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1957, 3 (3-4) :318-323

[3]

JUAN M, 1985, J CHEM SOC DA, V10, P2155

[4] Cation distribution, thermodynamic and kinetics considerations in nanoscaled copper ferrite spinels. New experimental approach by XPS and new results both in the bulk and on the grain boundary [J].

Kester, E ;

Gillot, B .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1998, 59 (08) :1259-1269

[5] Structural and transport properties of Mg1-xMnxMn2O4±δ spinels [J].

Malavasi, L ;

Ghigna, P ;

Chiodelli, G ;

Maggi, G ;

Flor, G .

JOURNAL OF SOLID STATE CHEMISTRY, 2002, 166 (01) :171-176

[6] Cation distribution in lithium nickel oxide crystals [J].

Monge, MA ;

Gutiérrez-Puebla, E ;

Martínez, JL ;

Rasines, I ;

Campa, JA .

CHEMISTRY OF MATERIALS, 2000, 12 (07) :2001-2007

[7] Distribution of metal ions and magnetic properties in spinel system CdCr2-xGaxSe4 [J].

Okonska-Kozlowska, I ;

Malicka, E ;

Waskowska, A ;

Heimann, J ;

Mydlarz, T .

JOURNAL OF SOLID STATE CHEMISTRY, 2001, 158 (01) :34-39

[8]

ONEILL HSC, 1983, AM MINERAL, V68, P181

[9]

ONEILL HSC, 1984, AM MINERAL, V69, P733

[10] THERMODYNAMICS OF MN3O4-CO3O4,FE3O4-MN3O4, AND FE3O4-CO3O4 SPINELS BY PHASE-DIAGRAM ANALYSIS [J].

PELTON, AD ;

SCHMALZRIED, H ;

STICHER, J .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1979, 83 (03) :241-252