Higher gas solubility in nanoliquids?

被引：56
作者：
Miachon, Sylvain [1 ]
Syakaev, Victor V. [1 ]
Rakhmatullin, Aydar [1 ]
Pera-Titus, Marc [1 ]
Caldarelli, Stefano [2 ]
Dalmon, Jean-Alain [1 ]
机构：
[1] Univ Lyon 1, CNRS, Inst Rech Catalyse & Environm Lyon, UMR5256, F-69626 Villeurbanne, France
[2] Univ Aix Marseille 1, JE 2421 TRACES, F-13013 Marseille, France
来源：
CHEMPHYSCHEM | 2008年 / 9卷 / 01期
关键词：
gas solubility; hydrocarbons; hydrogen; mesoporous materials; NMR spectroscopy;
D O I：
10.1002/cphc.200700638
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
(Graph Presented) Beyond Henry's law: In nanometer-confining media, gas solubility increases widely (see figure). H2, CH4 and C2H6 solubility values in two solvents are obtained by quantitative 1H NMR spectroscopy. A mass-balance model involving the gas-liquid interface zone agrees well with the observed variation. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：78 / 82
页数：5
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