Magnesium hydride-promoted dearomatisation of pyridine

被引：64

作者：

Hill, Michael S. ^{[1
]}

MacDougall, Dugald J. ^{[1
]}

Mahon, Mary F. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 46期

基金：

英国工程与自然科学研究理事会;

关键词：

BETA-DIKETIMINATE LIGAND; N-HETEROCYCLES; COMPLEXES; ADDUCT; BUTYLLITHIUM; SYSTEMS; METAL;

D O I：

10.1039/c0dt01246g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation of magnesium compounds containing 1,2- and 1,4-dihydropyridide anions as the respective kinetic and thermodynamic products.

引用

收藏

页码：11129 / 11131

页数：3

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