CLOUD POINT IN NON-IONIC SURFACTANTS PROBED BY ELECTRICAL IMPEDANCE SPECTROSCOPY

被引:2
作者
de Lima, Sandro Vagner [1 ]
de Oliveira, Helinando Pequeno [1 ]
机构
[1] Univ Fed Vale Sao Francisco, Colegiado Posgrad Ciencia Mat, BR-48902300 Juazeiro, BA, Brazil
来源
QUIMICA NOVA | 2010年 / 33卷 / 09期
关键词
electrical impedance spectroscopy; cloud point; non-ionic surfactants; PROMETHAZINE HYDROCHLORIDE; DIELECTRIC-SPECTROSCOPY; AMPHIPHILIC DRUGS; ADDITIVES; EXTRACTION; POLYPYRROLE; ALCOHOL; WATER;
D O I
10.1590/S0100-40422010000900020
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CLOUD POINT IN NON-IONIC SURFACTANTS PROBED BY ELECTRICAL IMPEDANCE SPECTROSCOPY. In this paper, we analyze the use of electrical impedance spectroscopy applied to determination of cloud point. The slope of admittance measured at 100 kHz is reduced to temperature above the critical value which characterizes the phase transition, in a strong indication that this process is activated during the clouding. Additionally to this study we explored the influence of parameters such as additives and temperature on the performance of phase separation of residues (silver nanoparticles) by cloud point extraction. The interaction with salt maximizes the separation of chemical residues in a progressively reduced temperature.
引用
收藏
页码:1928 / 1932
页数:5
相关论文
共 50 条
[11]   Combined Use of Ozonation and Biodegradation of Anionic and Non-ionic Surfactants [J].
Lechuga, Manuela ;
Fernandez-Arteaga, Alejandro ;
Fernandez-Serrano, Mercedes ;
Jurado, Encarnacion ;
Burgos, Alejandro ;
Rios, Francisco .
JOURNAL OF SURFACTANTS AND DETERGENTS, 2014, 17 (02) :363-370
[12]   Non-ionic surfactants adsorption: structure and thermodynamics [J].
Levitz, PE .
COMPTES RENDUS GEOSCIENCE, 2002, 334 (09) :665-673
[13]   Effect of non-ionic surfactants on transient cavitation in a megasonic field [J].
Keswani, M. ;
Raghavan, S. ;
Deymier, P. .
ULTRASONICS SONOCHEMISTRY, 2013, 20 (01) :603-609
[14]   Reactivity of two models of non-ionic surfactants with ozone [J].
Brambilla, A ;
Bolzacchini, E ;
Orlandi, M ;
Polesello, S ;
Rindone, B .
WATER RESEARCH, 1997, 31 (08) :1839-1846
[15]   Electrostatic effects in films stabilised by non-ionic surfactants [J].
Marquez-Beltran, Cesar ;
Langevin, Dominique .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 312 (01) :47-51
[16]   Ozonation impact on degradation and toxicity of non-ionic surfactants [J].
Ledakowicz, S ;
Perkowski, J ;
Bulska, A ;
Jamroz, T ;
Senciol, B .
OZONE-SCIENCE & ENGINEERING, 2005, 27 (06) :437-445
[17]   Degradation of non-ionic surfactants by advanced oxidation processes [J].
Perkowski, Jan ;
Sidor, Magdalena .
OCHRONA SRODOWISKA, 2007, 29 (01) :19-25
[18]   Aggregation of methyl orange probed by electrical impedance spectroscopy [J].
de Oliveira, H. P. ;
Oliveira, E. G. L. ;
de Melo, C. P. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 303 (02) :444-449
[19]   Separation and recycling of nanoparticles using cloud point extraction with non-ionic surfactant mixtures [J].
Nazar, Muhammad Faizan ;
Shah, Syed Sakhawat ;
Eastoe, Julian ;
Khan, Asad Muhammad ;
Shah, Afzal .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 363 (02) :490-496
[20]   The cloud point extraction of copper(II) with monocarboxylic acids into non-ionic surfactant phase [J].
Kulichenko, SA ;
Doroschuk, VO ;
Lelyushok, SO .
TALANTA, 2003, 59 (04) :767-773