Releasing Nanocapsules for High-Throughput Printing of Stable Perovskite Solar Cells

被引：32

作者：

Huang, Zengqi ^{[1
]}

Hu, Xiaotian ^{[2
]}

Zhao, Zhipeng ^{[1
,3
]}

Meng, Xiangchuan ^{[2
,4
]}

Su, Meng ^{[1
]}

Xue, Tangyue ^{[1
]}

Chi, Jimei ^{[1
,3
]}

Xie, Hongfei ^{[1
,3
]}

Cai, Zheren ^{[1
,3
]}

Chen, Yiwang ^{[4
]}

Li, Lin ^{[5
]}

Song, Yanlin ^{[1
,3
]}

机构：

[1] Chinese Acad Sci ICCAS, Key Lab Green Printing, Inst Chem, Zhongguancun North First St 2, Beijing 100190, Peoples R China

[2] Nanchang Univ, Coll Chem, 999 Xuefu Ave, Nanchang 330031, Jiangxi, Peoples R China

[3] Univ Chinese Acad Sci, Natl Lab Mol Sci BNLMS, 19 A Yuquan Rd, Beijing 100049, Peoples R China

[4] Jiangxi Normal Univ, Key Lab Funct Organ Small Mol, Minist Educ, 99 Ziyang Ave, Nanchang 330022, Jiangxi, Peoples R China

[5] Suzhou Univ Sci & Technol, Res Ctr Green Printing Nanophoton Mat, Sch Mat Sci & Engn, Suzhou 215009, Peoples R China

来源：

ADVANCED ENERGY MATERIALS | 2021年 / 11卷 / 34期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

diffusion-controlled growth; high-throughput printing; perovskite nanocapsules; solar cells; stability; HIGH-EFFICIENCY; SOLVENT; STABILITY; SILANE; FILMS;

D O I：

10.1002/aenm.202101291

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Perovskite solar cells (PSCs) are promising photovoltaic technologies due to their impressive power conversion efficiency (PCE) and low-temperature fabrication process, while it is still challenging to print uniform perovskite film with high crystalline quality over a module size. Here, a printable and stable perovskite nanocapsules ink to realize the high-throughput printing of large-area, highly uniform perovskite films with micron grain size is reported. It is discovered that the releasing effect of these perovskite nanocapsules promotes homogeneous nucleation by diffusion-controlled growth due to the steady-state diffusion of the solute in solution. Remarkably, the printed PSCs and 25 cm(2) modules achieve power conversion efficiencies of 22.10% and 16.12%, respectively. They exhibit negligible efficiency loss after continuous operation for over 1000 h under AM1.5 illumination, and excellent thermal (85 degrees C) stability with over 87% of the initial efficiency after aging for 500 h. This perovskite nanocapsules ink is expected to facilitate the high-yield fabrication of perovskite photovoltaics.

引用

页数：11

共 54 条

[41]

Sugimoto T., 2001, Monodispersed Particles

[42] Efficient Inverted Perovskite Solar Cells with Low Voltage Loss Achieved by a Pyridine-Based Dopant-Free Polymer Semiconductor [J].