Evidence for a New Two-Dimensional C4H-Type Polymer Based on Hydrogenated Graphene

被引：99

作者：

Haberer, Danny ^{[1
]}

Giusca, Cristina E. ^{[2
]}

Wang, Ying ^{[3
]}

Sachdev, Hermann ^{[4
,5
]}

Fedorov, Alexander V. ^{[6
]}

Farjam, Mani ^{[7
]}

Jafari, S. Akbar ^{[7
,8
]}

Vyalikh, Denis V. ^{[9
]}

Usachov, Dmitry ^{[6
]}

Liu, Xianjie ^{[10
]}

Treske, Uwe ^{[1
]}

Grobosch, Mandy ^{[1
]}

Vilkov, Oleg ^{[9
]}

Adamchuk, Vera K. ^{[6
]}

Irle, Stephan ^{[3
]}

Silva, S. Ravi P. ^{[2
]}

Knupfer, Martin ^{[1
]}

Buechner, Bernd ^{[1
]}

Grueneis, Alexander ^{[1
,10
]}

机构：

[1] IFW Dresden, D-01171 Dresden, Germany

[2] Univ Surrey, Adv Technol Inst, Guildford GU2 7XH, Surrey, England

[3] Nagoya Univ, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[4] Univ Saarland, D-66041 Saarbrucken, Germany

[5] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

[6] St Petersburg State Univ, St Petersburg 198504, Russia

[7] Inst Res Fundamental Sci IPM, Tehran, Iran

[8] Sharif Univ Technol, Dept Phys, Tehran 111559161, Iran

[9] Tech Univ Dresden, Inst Festkorperphys, D-01069 Dresden, Germany

[10] Univ Vienna, Fac Phys, A-1090 Vienna, Austria

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 39期

基金：

日本科学技术振兴机构;

关键词：

PHOTOEMISSION; MONOLAYER;

D O I：

10.1002/adma.201102019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new polymer with C4H stoichiometry based on graphene is synthesized in situ using template-induced polymerization of self-organizing hydrogen adsorbates on graphene. The polymerization is observed "live" on the surface of graphene by photoemission spectroscopy. Photoemission spectroscopy allows accurate determination of the carbon/hydrogen stoichiometry, an aspect that is extremely important for understanding functionalized graphene.

引用

页码：4497 / +

页数：8

共 45 条

[1]

Balog R, 2010, NAT MATER, V9, P315, DOI [10.1038/nmat2710, 10.1038/NMAT2710]

[2] Atomic Hydrogen Adsorbate Structures on Graphene [J].