Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides

被引：2
|
作者：
Fischer, Roland [1 ]
Marschner, Christoph [1 ]
机构：
[1] Graz Univ Technol, Inst Anogan Chem, A-8010 Graz, Austria
来源：
MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 01期
关键词：
stannylated compounds; group; 4; elements; metallocenes; stannylene; tin; silicon; zirconium; hafnium; DERIVATIVES; MECHANISM; POLYMERIZATION; TRIMETHYLSILYL; POLYSILANES; REACTIVITY; ZIRCONIUM; COMPLEXES; HAFNIUM; SILANES;
D O I：
10.1016/j.mencom.2022.01.016
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of (Me3Si)(3)SnK with Cp2MCl2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp2M(Cl)SiMe3 formation.
引用
收藏
页码：52 / 53
页数：2
相关论文
共 36 条
  • [31] One-Pot Synthesis of Spirotetrahydrooxino[3,4-c]pyridines and Spirotetrahydrofuro[3,2-b]pyridin-2-ones via Lactonization from Activated Pyridyldihydroozaxoles and Bis(trimethylsilyl)ketene Acetals
    Gomez-Garcia, Omar
    Gomez, Elizabeth
    Toscano, Ruben A.
    Salgado-Zamora, Hector
    Alvarez-Toledano, Cecilio
    SYNTHESIS-STUTTGART, 2016, 48 (09): : 1371 - 1380
  • [32] Cooperative Palladium and Copper Catalysis: One-pot Synthesis of Diamino-Substituted Naphthalenes from Aryl Halides, 1,4-Bis(trimethylsilyl)butadiyne and Amines
    Li, Yuan
    Qiu, Shaozhong
    Fan, Ling
    Yin, Guodong
    CHEMCATCHEM, 2020, 12 (04) : 1230 - 1235
  • [33] Different Inertness of Titanocene [Cp2Ti] and Decamethyltitanocene [Cp*2Ti] in Reactions with N,N-Bis(trimethylsilyl)sulfurdiimide - Elimination of Tetramethyl-fulvene and Formation of Half-Titanocene Complexes
    Kaleta, Katharina
    Kessler, Monty
    Beweries, Torsten
    Arndt, Perdita
    Spannenberg, Anke
    Rosenthal, Uwe
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (21) : 3388 - 3393
  • [34] Intramolecularly donor-stabilized silenes: Part 5. Generation and conversion of 1-[2,6-bis(alkoxymethyl)phenyl]- and 1-(8-alkoxynaphthyl)-1,2,2-tris(trimethylsilyl)silenes
    Mamat, C
    Mickoleit, M
    Reinke, H
    Oehme, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (10) : 1739 - 1745
  • [35] Preparation and characterization of bis-(trimethylsilyl)aminoalanes [H2AlN(SiMe3)(2)]center dot NMe3 and {HA1[N(SiMe3)(2)](2)}(n) - Crystal structure determination for tris-(trimethylsilyl)alane trimethylamine adduct (Me3Si)(3)Al center dot NMe3
    Janik, JF
    Duesler, EN
    Paine, RT
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 539 (1-2) : 19 - 25
  • [36] New Characterization of V{N(SiMe3)2}3: Reductions of Tris[bis(trimethylsilyl)amido]vanadium(III) and -chromium(III) To Afford the Reduced Metal(II) Anions [M{N(SiMe3)2}3]- (M = V and Cr)
    Wagner, Clifton L.
    Phan, Nathan A.
    Fettinger, James C.
    Berben, Louise A.
    Power, Philip P.
    INORGANIC CHEMISTRY, 2019, 58 (09) : 6095 - 6101
1234