Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides

被引：2

作者：

Fischer, Roland ^{[1
]}

Marschner, Christoph ^{[1
]}

机构：

[1] Graz Univ Technol, Inst Anogan Chem, A-8010 Graz, Austria

来源：

MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 01期

关键词：

stannylated compounds; group; 4; elements; metallocenes; stannylene; tin; silicon; zirconium; hafnium; DERIVATIVES; MECHANISM; POLYMERIZATION; TRIMETHYLSILYL; POLYSILANES; REACTIVITY; ZIRCONIUM; COMPLEXES; HAFNIUM; SILANES;

D O I：

10.1016/j.mencom.2022.01.016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of (Me3Si)(3)SnK with Cp2MCl2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp2M(Cl)SiMe3 formation.

引用

页码：52 / 53

页数：2

共 36 条

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