Facile one-step synthesis of bio-based AESO resins

被引：24

作者：

Wang, Chengshuang ^{[1
]}

Ding, Liang ^{[1
]}

He, Meng ^{[1
]}

Wei, Jun ^{[1
]}

Li, Juan ^{[1
]}

Lu, Rong ^{[1
]}

Xie, Hongfeng ^{[2
]}

Cheng, Rongshi ^{[2
,3
]}

机构：

[1] Yancheng Inst Technol, Sch Mat Engn, Yancheng 224051, Peoples R China

[2] Nanjing Univ, Key Lab High Performance Polymer Mat & Technol, Minist Educ, Sch Chem & Chem Engn, Nanjing, Jiangsu, Peoples R China

[3] South China Univ Technol, Coll Mat Sci & Engn, Guangzhou, Guangdong, Peoples R China

来源：

EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY | 2016年 / 118卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Acrylated soybean oil; Thermosetting resins; Thiol-ene coupling; SOYBEAN-OIL; VEGETABLE-OILS; THERMOSETTING POLYMERS; MECHANICAL-PROPERTIES; PLANT OILS; THIOL; ACID; CHEMISTRY; NETWORKS; MONOMERS;

D O I：

10.1002/ejlt.201500494

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

In this study, the bio-based thermosetting resins were synthesized via thiol-ene coupling between acrylated epoxidized soybean oil (AESO) and different functionality of thiols. The structure of the AESO was carefully examined using FT-IR and H-1-NMR measurements. The thermal/mechanical properties of the bio-based thermosetting resins were characterized using DMA, TGA, and tensile test. The DMA results showed that the storage moduli and glass transition temperatures of bio-based thermosetting resins improved with increment of thiols functionality, meanwhile, the tensile strength, Young's modulus, and thermal stability of the AESO-based resins also increased.

引用

页码：1463 / 1469

页数：7

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