Facile preparation of bicyclo[2.2.2]octenone derivatives via Diels-Alder cycloadditions of in situ-generated masked o-benzoquinones

被引：9
作者：
Kalogiros, Christos [1 ]
Hadjiarapoglou, Lazaros P. [1 ]
机构：
[1] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece
来源：
TETRAHEDRON | 2011年 / 67卷 / 18期
关键词：
2,2-Dimethoxycyclohexa-3,5-dienone; retro-Diels-Alder/Diels-Alder; cycloaddition; Masked o-benzoquinone; Phenol oxidation; STEREOSELECTIVE-SYNTHESIS; EFFICIENT; OXIDATION; MONOKETALS; ACID; CYCLOHEXA-2,4-DIENONES; HETEROCYCLES; TRIQUINANES; ADDUCTS; EUGENOL;
D O I：
10.1016/j.tet.2011.03.018
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Diels-Alder cycloadditions of in situ-generated, substituted 2,2-dimethoxycyclohexa-3,5-dienones with olefinic dienophiles resulted in the development of an efficient method for the preparation of highly functionalized bicyclo[2.2.2]oct-5-en-2-ones with good to excellent yields. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3216 / 3225
页数：10
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