Elucidation of Phase Equilibria in Quinary Na,K,Mg//SO4,B4O7-H2O System at 15°C

被引:7
作者
Tursunbadalov, Sh. [1 ]
机构
[1] Nile Univ Nigeria, FNAS, Dept Chem, Res & Inst Area, Plot 681, Fct Abuja 900001, Nigeria
关键词
quinary system; phase equilibria; total phase equilibria diagram; crystallization volume; SOLID-LIQUID EQUILIBRIA; NA; K; MG; CA-PARALLEL-TO-SO4; CL-H2O SYSTEM; CRYSTALLIZATION; 50-DEGREES-C; NA+;
D O I
10.1134/S0036023620030195
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Results of investigation of phase equilibria in quinary Na,K,Mg//SO4,B4O7-H2O system at 15 degrees C by means of translation method were discussed. Total phase equilibria diagram of the system was fragmented into divariant co-crystallization fields of two solid phases and trivariant crystallization volumes of individual solid phases. Crystallization volumes form the structures of dry-salt diagrams of the system saturated with relevant phases. The results obtained agree and involve the recent experimental results on MgB4O7 . 9H(2)O saturated part of the quinary Na,K,Mg//SO4,B4O7-H2O system at 15 degrees C.
引用
收藏
页码:412 / 419
页数:8
相关论文
共 25 条
[1]   THE SYSTEM POTASSIUM SULFATE SODIUM SULFATE MAGNESIUM SULFATE WATER AT 35-DEGREES [J].
BAYLISS, NS ;
COLE, ARH ;
EWERS, WE ;
JONES, NK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (08) :2033-2036
[2]   Solid-liquid equilibrium for the ternary systems (Na2CO3+ NaCl + H2O) and (Na2CO3+ Na2SO4+ H2O) at 313.15 K and atmospheric pressure [J].
Cao, Jing ;
Ren, Yongsheng ;
Yu, Bingjie ;
Qiu, Lingshu ;
Ma, FeiYan .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2019, 133 :181-193
[3]   Investigation of Solid-Liquid Equilibria on the Na+//CI-, NO3-, SO42--H2O System and the Na+//NO3-, SO42--H2O System at 313.15 K [J].
Cao, Jing ;
Ren, Yongsheng ;
Zhu, Qiunan ;
Ma, Yulong .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2019, 64 (03) :1209-1221
[4]   Solid-Liquid Equilibria for (NaNO3 + NaCl + H2O) and (NaNO3 + Na2CO3 + H2O) Systems at 313.15 K [J].
Cao, Jing ;
Ding, Manxin ;
Ren, Yongsheng .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2019, 64 (03) :884-894
[5]  
Deng T., 2012, ADV CRYSTALLIZATION, DOI [10.5772/35619, DOI 10.5772/35619]
[6]  
Goroshchenko Y. G., 1982, CENTROID METHOD IMAG
[7]   Solid-Liquid Stable Equilibria for the Quaternary Na2B4O7-Na2SO4-K2B4O7-K2SO4-H2O System at 288 K [J].
Sang, Shi Hu ;
Li, Heng ;
Sun, Ming-Liang ;
Peng, Jiang .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (05) :1956-1959
[8]   (Solid liquid) equilibria in the quinary system Na+, Mg2+, K+//SO42-, B4O72--H2O at 288 K [J].
Sang, Shi-Hua ;
Peng, Jiang .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2010, 34 (01) :64-67
[9]   Solid-liquid phase equilibrium and phase diagram for the reciprocal quaternary system Na+, K+//SO42,H2PO4- - H2O at 313.15 K [J].
Shen, Wei ;
Ren, Yongsheng ;
Sun, Jiajin .
FLUID PHASE EQUILIBRIA, 2016, 429 :196-204
[10]   Phase equilibria in the Na,K∥SO4,CO3,HCO3-H2O system at 25°C [J].
Soliev, L. ;
Tursunbadalov, Sh. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (05) :805-811