Unique Inclusion Properties of Crystalline Powder p-tert-Butylthiacalix[4]arene toward Alcohols and Carboxylic Acids

被引：29
作者：
Morohashi, Naoya [1 ]
Noji, Shintaro [1 ]
Nakayama, Hiroko [1 ]
Kudo, Yasutaka [1 ]
Tanaka, Shinya [1 ]
Kabuto, Chizuko
Hattori, Tetsutaro [1 ]
机构：
[1] Tohoku Univ, Grad Sch Engn, Dept Biomol Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 13期
关键词：
DIMERIC CAPSULES; GUEST INCLUSION; COMPLEXATION; CALIXARENE; PURIFICATION; RECOGNITION; SULFOXIDES; MOLECULES; CHEMISTRY; HYDROGEN;
D O I：
10.1021/ol200506p
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Powdery crystals of p-tert-butylthiacalix[4]arene (2) selectively include EtOH from 1:1 mixtures of MeOH-EtOH and EtOH-PrOH, and EtCO2H from HCO2H-EtCO2H. On the other hand, no acid is included from HCO2H-MeCO2H, even though MeCO2H is included from the neat acid. The origins of these phenomena are discussed based on X-ray analysis of inclusion crystals prepared separately by crystallization.
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收藏
页码：3292 / 3295
页数：4
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