Chirality Recognition in Menthol and Neomenthol: Preference for Homoconfigurational Aggregation

被引：24

作者：

Albrecht, Merwe ^{[1
]}

Will, Jan ^{[1
]}

Suhm, Martin A. ^{[1
]}

机构：

[1] Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 35期

关键词：

dimers FT-IR spectroscopy; menthol; molecular recognition; hydrogen bonding; GAS-PHASE; SPECTROSCOPY;

D O I：

10.1002/anie.201001565

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cool chirality: L-Menthol (see ball-and-stick model), a most important fragrance, is characterized in terms of its conformation, selective aggregation, and sublimation. The data indicate a preference for homoconfigured aggregates. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6203 / 6206

页数：4

共 26 条

[21] THERMAL ANALYTICAL INVESTIGATIONS ON MENTHOLS [J].

KUHNERTB.M ;

ULMER, R ;

LANGHAMM.L .

ARCHIV DER PHARMAZIE, 1974, 307 (07) :497-503

[22] Identification of a cold receptor reveals a general role for TRP channels in thermosensation [J].

McKemy, DD ;

Neuhausser, WM ;

Julius, D .

NATURE, 2002, 416 (6876) :52-58

[23] Menthol: A refreshing look at this ancient compound [J].

Patel, Tejesh ;

Ishiuji, Yozo ;

Yosipovitch, Gil .

JOURNAL OF THE AMERICAN ACADEMY OF DERMATOLOGY, 2007, 57 (05) :873-878

[24] HYDROGEN BOND DYNAMICS IN ALCOHOL CLUSTERS [J].

Suhm, Martin A. .

ADVANCES IN CHEMICAL PHYSICS, VOL 142, 2009, 142 :1-57

[25] Structural preferences, argon nanocoating, and dimerization of n-alkanols as revealed by OH stretching spectroscopy in supersonic jets [J].

Wassermann, Tobias N. ;

Zielke, Philipp ;

Lee, Juhyon J. ;

Cezard, Christine ;

Suhm, Martin A. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (31) :7437-7448

[26] Chirality recognition between neutral molecules in the gas phase [J].

Zehnacker, Anne ;

Suhm, Martin A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (37) :6970-6992

← 1 2 3 →