Photocatalytic Self Cleaning Textile Fibers by Coaxial Electrospinning

被引:123
作者
Bedford, N. M. [1 ,3 ]
Steckl, A. J. [1 ,2 ]
机构
[1] Univ Cincinnati, Nanoelect Lab, Cincinnati, OH 45221 USA
[2] Univ Cincinnati, Dept Elect & Comp Engn, Cincinnati, OH 45221 USA
[3] Univ Cincinnati, Dept Chem & Mat Engn, Cincinnati, OH 45221 USA
关键词
coaxial electrospinning; textile fibers; photocatalysis; self-cleaning; TiO2; CRYSTAL-STRUCTURE; TIO2; CELLULOSE; NANOFIBERS; FABRICATION; COMPOSITE; MEMBRANES; TITANIUM; SOLVENT; SURFACE;
D O I
10.1021/am1005089
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Photocatalytic self cleaning textile fibers have been created using coaxial electrospinning. This is accomplished by electrospinning cellulose acetate as the core phase and a dispersion of nanocrystalline TiO2, a well-known photocatalyst, in the sheath phase. A simple deacetylation step after the initial electrospinning yields self-cleaning textile fibers. Self-cleaning activity is exhibited at moderate power densities in indoor lighting conditions. Nanofibers created from coaxial electrospinning outperform TiO2 surface loaded nanofibers obtained by conventional electrospinning. Surface-loaded fibers degrade blue dye stains only to a minimum of 20 % of the initial concentration, whereas fibers created by coaxial electrospinning fully degrade stains (in 7-8 h).
引用
收藏
页码:2448 / 2455
页数:8
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