Synthesis and characterization of potassium iodo hydride

被引：49

作者：

Mills, RL ^{[1
]}

Dhandapani, B ^{[1
]}

Greenig, N ^{[1
]}

He, JL ^{[1
]}

机构：

[1] BlackLight Power Inc, Cranbury, NJ 08512 USA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2000年 / 25卷 / 12期

关键词：

Potassium iodo hydrides;

D O I：

10.1016/S0360-3199(00)00037-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel inorganic hydride compound KHI which comprises a high binding energy hydride ion was synthesized by reaction of atomic hydrogen with potassium metal and potassium iodide. Potassium iodo hydride was identified by time-of-flight secondary ion mass spectroscopy, X-ray photoelectron spectroscopy, H-1 and K-39 nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, electrospray ionization time-of-flight mass spectroscopy, liquid chromatography/mass spectroscopy, thermal decomposition with analysis by gas chromatography, and mass spectroscopy, and elemental analysis. Hydride ions with increased binding energies may form many novel compounds with broad applications. (C) 2000 International Association for Hydrogen Energy. Published by Elsevier Science Ltd. All rights reserved.

引用

页码：1185 / 1203

页数：19

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