Ba4Mo12S18:: A superconductor containing the dimeric unit (Mo6)2S24, the missing link between the Mo6S14 and Mo9S17 units

被引：7

作者：

Salloum, D ^{[1
]}

Gautier, R ^{[1
]}

Potel, M ^{[1
]}

Gougeon, P ^{[1
]}

机构：

[1] Univ Rennes 1, ENSC Rennes, CNRS, Inst Chim Rennes,Lab Chim Solide & Inorgan Mol,UM, F-35042 Rennes, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 09期

关键词：

barium; cluster compounds; molybdenum; solid-state structures; superconductors;

D O I：

10.1002/anie.200461255

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New structural type: The three-dimensional Mo-S framework of the solid-state compound Ba4Mo12S18 contains the novel dimeric (Mo6)2S24 unit (picture, middle). This can be regarded as the result of fusing two octahedral MO 6S14 units (left) and as the intermediate step towards formation of the bioctahedral Mo9S17 unit (right). Ba 4Mo12S18 was found to be a superconductor with a transition temperature of 7 K. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1363 / 1365

页数：3

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