Electronic excited states of NO/Cu(111) studied by high-resolution two-photon photoelectron spectroscopy

被引：6
作者：
Munakata, T [1 ]
Sakashita, T [1 ]
Tsukakoshi, M [1 ]
Nakamura, J [1 ]
机构：
[1] SCI UNIV TOKYO, SHINJUKU KU, TOKYO 162, JAPAN
来源：
SURFACE SCIENCE | 1996年 / 357卷 / 1-3期
关键词：
copper; nitrogen oxides; surface electronic phenomena; visible and ultraviolet photoelectron spectroscopy;
D O I：
10.1016/0039-6028(96)00235-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A high-resolution two-photon photoelectron (2PPE) spectrometer was constructed and applied to NO adsorbed Cu(111). The apparatus was based on a high-repetitive tunable laser of picosecond pulse duration combined with a single-electron counting time-of-flight (TOF) system. Performance of the apparatus was examined with 2PPE spectra of Ag(111) and Cu(111) surfaces, Energy resolution better than 0.03 eV was achieved. A preliminary result for NO adsorbed Cu(111) surface showed that electronic states of adsorbed NO contain some fine structures, suggesting that the high-resolution 2PPE spectroscopy provides much information on electronic structure of adsorbed molecules.
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页码：629 / 633
页数：5
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