Preparation and energy storage application of a long-life and high rate performance pseudocapacitive COF material linked with -NH- bonds

A new covalent organic framework material (NWNU-COF-1) linked with -NH- bonds is synthesized by the condensation reaction of melamine and 2,4,6-trichloro-1,3,5-triazine and its structure and properties are characterized by Fourier transform infrared (FT-IR) spectroscopy, powder X-ray diffraction (XRD), thermogravimetric analysis (TGA), N-2 adsorption-desorption, X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The BET specific surface area of NWNU-COF-1 is 301.149 m(2) g(-1), and the pore size is about 1.41 nm. The preparation is also simple and cheap. This material exhibits a significant pseudocapacitance characteristic in a 6 M potassium hydroxide electrolyte, and the highest specific capacitance value of 155.38 F g(-1) at 0.25 A g(-1) current density in a three electrode configuration. This COF also demonstrates about 100% capacitance retention after 20000 galvanostatic charge-discharge cycles, which is equal, even better compared with the COF materials reported previously, the nano/mesoporous carbon materials and even nitrogen doped carbons.