Density and viscosity studies of binary mixtures of acetonitrile with methanol, ethanol, propan-1-ol, propan-2-ol, butan-1-ol, 2-methylpropan-1-ol, and 2-methylpropan-2-ol at (298.15, 303,15, 308.15, and 313.15) K

被引:269
作者
Nikam, PS [1 ]
Shirsat, LN [1 ]
Hasan, M [1 ]
机构
[1] MSG Coll, Dept Chem Phys, Malegaon Camp 423105, India
关键词
D O I
10.1021/je980028e
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities have been measured for the binary mixtures of acetonitrile with linear and brached alkanols (C-1-C-4) over the entire composition range at (298.15, 303.15, 308.15, and 313.15) K. The experimental density (rho) and viscosity (eta) values were used to calculate the excess molar volume (V-E) and viscosity deviation (Delta eta) The effects of chain length and branching of alkanols on V-E and Delta eta values have been discussed. The V-E and Delta eta values are fitted to a Redlich-Kister equation.
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页码:732 / 737
页数:6
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