One-pot synthesis of non-symmetric tetraoxanes with the H2O2/MTO/fluorous alcohol system

被引：81
作者：
Iskra, J
Bonnet-Delpon, D [1 ]
Bégué, JP
机构：
[1] Univ Paris 11, Fac Pharm, BIOCIS UPRESA 8079, F-92290 Chatenay Malabry, France
[2] Jozef Stefan Inst, Organ & Bioorgan Chem Lab, Ljubljana, Slovenia
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 33期
关键词：
D O I：
10.1016/S0040-4039(03)01472-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1,2,4,5-Tetraoxanes, potent antimalarial drugs, were selectively synthesized in fluorous alcohols (2,2,2-trifluoroethanol-TFE and 1,1,1,3,3,3-hexafluoro-2-propanol-HFIP). A use of these solvents enabled for the first time a one-pot synthesis of non-symmetric tetraoxanes in good yields from simple ketones and aldehydes with 2 equiv. of 30% hydrogen peroxide and 0.1 mol% of methyltrioxorhenium (MTO). (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6309 / 6312
页数：4
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