A Zn based coordination polymer exhibiting long-lasting phosphorescence

被引：43
作者：
Cepeda, Javier [1 ,2 ]
San Sebastian, Eider [1 ]
Padro, Daniel [3 ]
Rodriguez-Dieguez, Antonio [4 ]
Garcia, Jose A. [5 ]
Ugalde, Jesus M. [6 ,7 ]
Seco, Jose M. [1 ]
机构：
[1] Univ Basque Country, Fac Chem, Dept Appl Chem, UPV EHU, Donostia San Sebastian 20080, Spain
[2] Univ Basque Country, Fac Chem, Polymer Sci & Technol Dept, UPV EHU, Donostia San Sebastian 20080, Spain
[3] CIC BiomaGUNE, Nucl Magnet Resonance Platform, Donostia San Sebastian 20080, Spain
[4] Univ Granada, Fac Chem, Dept Inorgan Chem, E-18071 Granada, Spain
[5] Univ Basque Country, UPV EHU, Fac Sci & Technol, Dept Appl Phys, Bilbao 48940, Spain
[6] Euskal Herriko Unibertsitatea UPV EHU, Kimika Fak, PK 1072, Donostia San Sebastian 20080, Euskadi, Spain
[7] Donostia Int Phys Ctr, PK 1072, Donostia San Sebastian 20080, Euskadi, Spain
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 56期
关键词：
METAL-ORGANIC FRAMEWORKS; EXCITATION-ENERGIES; CRYSTAL-STRUCTURES; LUMINESCENCE; COMPLEXES; APPROXIMATION; NETWORK;
D O I：
10.1039/c6cc03242g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new Zn(II) based coordination polymer (CP) built by the cohesive pilling of 2D Shubnikov type layers is reported. This material exhibits time dependent multicoloured emission, part of which shows a persistent green phosphorescence visible for up to two seconds to the naked eye, which originates from multiple charge transfer mechanisms.
引用
收藏
页码：8671 / 8674
页数：4
相关论文
共 33 条
[1]   The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].
Allen, FH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388
[2]   Highly efficient phosphorescent emission from organic electroluminescent devices [J].
Baldo, MA ;
O'Brien, DF ;
You, Y ;
Shoustikov, A ;
Sibley, S ;
Thompson, ME ;
Forrest, SR .
NATURE, 1998, 395 (6698) :151-154
[3]   Luminescent complexes beyond the platinum group:: the d10 avenue [J].
Barbieri, Andrea ;
Accorsi, Gianluca ;
Armaroli, Nicola .
CHEMICAL COMMUNICATIONS, 2008, (19) :2185-2193
[4]   Vertex-, face-, point-, Schlafli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology [J].
Blatov, V. A. ;
O'Keeffe, M. ;
Proserpio, D. M. .
CRYSTENGCOMM, 2010, 12 (01) :44-48
[5]   Applied Topological Analysis of Crystal Structures with the Program Package ToposPro [J].
Blatov, Vladislav A. ;
Shevchenko, Alexander P. ;
Proserpio, Davide M. .
CRYSTAL GROWTH & DESIGN, 2014, 14 (07) :3576-3586
[6]   A critical review of the development of the CIE1931 RGB color-matching functions [J].
Broadbent, AD .
COLOR RESEARCH AND APPLICATION, 2004, 29 (04) :267-272
[7]   Long lifetime photoluminescence emission of 3D cadmium metal-organic frameworks based on the 5-(4-pyridyl)tetrazole ligand [J].
Calahorro, Antonio J. ;
Salinas-Castillo, Alfonso ;
Fairen-Jimenez, David ;
Seco, Jose M. ;
Mendicute-Fierro, Claudio ;
Gomez-Ruiz, Santiago ;
Lopez-Viseras, Marta E. ;
Rodriguez-Dieguez, Antonio .
INORGANICA CHIMICA ACTA, 2015, 427 :131-137
[8]   Self-assembly of a three-dimensional network from two-dimensional layers via metallic spacers: The (3,4)-connected frame of [Ag-3(hmt)(2)][ClO4](3)center dot 2H(2)O (hmt equals hexamethylenetetramine) [J].
Carlucci, L ;
Ciani, G ;
vonGudenberg, DW ;
Proserpio, DM ;
Sironi, A .
CHEMICAL COMMUNICATIONS, 1997, (06) :631-632
[9]   Molecular excitation energies to high-lying bound states from time-dependent density-functional response theory: Characterization and correction of the time-dependent local density approximation ionization threshold [J].
Casida, ME ;
Jamorski, C ;
Casida, KC ;
Salahub, DR .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (11) :4439-4449
[10]   Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles [J].
Dhakshinamoorthy, Amarajothi ;
Garcia, Hermenegildo .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5750-5765
1234