Experimental and kinetic modeling investigation of toluene combustion in premixed, one-dimensional and laminar toluene-oxygen-argon flames

被引：30
作者：
Detilleux, Valery [1 ]
Vandooren, Jacques [1 ]
机构：
[1] Catholic Univ Louvain, Inst Condensed Matter & Nanosci IMCN, Mol Solids & React MOST, B-1348 Louvain, Belgium
来源：
PROCEEDINGS OF THE COMBUSTION INSTITUTE | 2011年 / 33卷
关键词：
Toluene; Flame; Oxidation; Kinetic; Model; HIGH-TEMPERATURE OXIDATION; HIGH-PRESSURE; BENZENE; MECHANISM;
D O I：
10.1016/j.proci.2010.06.151
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
One-dimensional, premixed and laminar toluene-oxygen-argon flames, with equivalence ratios of 0.7 and 1.0 were stabilized at low pressure on a flat flame burner. Mole fraction profiles of 18 chemical species have been measured by gas chromatography and molecular beam mass spectrometry. A kinetic model with a good predictive capability has been developed to compare with experimental data. A comparative reaction rate analysis of predicted flame structures has allowed us to determine main pathways of toluene combustion and their dependence on temperature and equivalence ratio. (C) 2010 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
引用
收藏
页码：217 / 224
页数：8
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