Pendent aminoaklyl-substituted monocyclopentadienyltitanium compounds and their polymerization behavior

被引：78

作者：

Blais, MS ^{[1
]}

Chien, JCW ^{[1
]}

Rausch, MD ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 17期

关键词：

D O I：

10.1021/om980118c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new aminoalkyl-substituted monocyclopentadienyltitanium trichloride compounds have been prepared that contain pyridyl (2-picolyl), diisopropylaminoethyl, dimethylaminoethyl, and phenylethyl ligands. Incorporation of these pendent ligands to corresponding (cyclopentadienyl)triisopropoxytitanium and (indenyl)triisopropoxytitanium complexes are also described, The utility of these complexes for the polymerization of ethylene, propylene and styrene has been investigated.

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页码：3775 / 3783

页数：9

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